Formula: LaB6
Alias / Keywords: Lanthanum Boride cathode components, LaB6 Cathode, (LaBa)B6, (LaEu)B6, CeB6, PrB6, NdB6, SmB6, EuB6, GdB6, DyB6, YbB6, YB6,
.
Lanthanum Boride cathode components
(rod, disc, tube, square.... customized shape and size)
Appearance intense purple violet
Crystal system: cubic
Grain structural: face-centered cubic lattice
Crystal Lattice Constant: 0.4153 a/nm
Density: 4.72 g/cm3
Melting point: 2715°C
Thermal conductivity: 144x10-3cal/(cm.°C.s)
Coefficient of linear expansion:5.6a x 10-6/°C
Characteristic temperature: 885K
Electronic work function: 2.87e
Microhardness: 2500kg/m2
Lanthanum Boride (LaB6, also called Lanthanum hexaboride and LaB) is an
inorganic chemical, a boride of lanthanum. It is a refractory ceramic material
that has a melting point of 2210 °C, is insoluble in water and hydrochloric
acid. It has a low work function and one of the highest electron emissivities
known, and is stable in vacuum. Stoichiometric samples are colored intense
purple-violet, while boron-rich ones (above LaB6.07) are blue. Ion bombardment
changes its color from purple to emerald green.
The principial use of lanthanum hexaboride is in hot cathodes, either as a
single crystal or as a coating deposited by physical vapor deposition.
Hexaborides, such as lanthanum hexaboride (LaB6) and cerium hexaboride (CeB6),
have low work functions, around 2.5 eV. They are also somewhat resistant to
cathode poisoning. Cerium hexaboride cathodes have a lower evaporation rate at
1700 K than lanthanum hexaboride, but they becomes equal at temperatures above
1850 K. Cerium hexaboride cathodes have one and half the lifetime of lanthanum
hexaboride, due to the former's higher resistance to carbon contamination.
Hexaboride cathodes are about ten times "brighter" than tungsten cathodes, and
have 10-15 times longer lifetime. They are used eg. in electron microscopes,
microwave tubes, electron lithography, electron beam welding, X-ray tubes, and
free electron lasers.
Lanthanum hexaboride slowly evaporates from the heated cathodes and forms
deposits on the Wehnelt cylinders and apertures.
Other Rare Earth Boride Cathode available, like:
(LaBa)B6
(LaEu)B6
CeB6
PrB6
NdB6
SmB6
EuB6
GdB6
DyB6
YbB6
YB6
and etc.